Environmental Sanitation Engineering ›› 2022, Vol. 30 ›› Issue (6): 46-57.doi: 10.19841/j.cnki.hjwsgc.2022.06.009

Previous Articles     Next Articles

Study on the Influence of Washing-Thermal Treatment on the Stabilization and Long-term Leaching of Pb, Zn, Cu in Fly Ash

LYU Zhong, XIA Yunxue, ZHANG Jianshuai, TANG Yuanyuan   

  1. School of Environmental Science and Engineering, Southern University of Science and Technology
  • Online:2023-01-04 Published:2023-01-04

Abstract: A combination of water washing pretreatment and thermal treatment may become a strategy for safe disposal and resource utilization of the MSW incineration fly ash. However, the influence of water washing on the migration and transformation of heavy metals has not been clearly studied, and the leaching risk of fly ash after disposal was underestimated by common leaching methods due to the strong buffering performance of fly ash. In view of the above problems, the curing mechanism of Pb, Zn and Cu in fly ash was studied, the influence of water pretreatment on the curing behavior of heavy metals was discussed. And a long-term leaching device with constant pH was designed to evaluate the long-term leaching behavior of fly ash after disposal. The results showed that the major product phases of Pb, Zn, Cu after the washing-thermal treatment were identified as lead-aluminosilicate, lead-calcium oxide, zinc silicate, zinc-aluminosilicate, etc. Meanwhile, the aforementioned phases were also detected in the scheme of only thermal treatment but with additional lead oxide chloride, lead aluminum oxide, lead silicate, zinc chloride and calcium copper oxide, etc. The types of Pb, Zn and Cu phases in fly ash after washing-thermal treatment were less affected by the sintering temperature and metal content. A higher Pb stabilization efficiency was obtained after washing-thermal treatment compared with only thermal treatmeat, with the value ranged from 94.59% to 99.60%. In the long-term leaching experiments with constant pH, the corresponding leachate pH of the two solutions were maintained in the range of 2.91~3.63 and 4.91~5.36. Leaching concentrations of Pb, Zn, Cu concentrations basically reached the maximum value after 600 mins, then decreased and maintained a low concentration at 0~0.09, 0.01~0.92, 0.03~0.22 mg/L(washing-thermal) and 0.03~0.31, 0.07~0.94, 0~0.11 mg/L (only thermal) respectively. The long-term leaching method proposed in this study could evaluate the long-term leaching risk of fly ash under extreme conditions, reveal the migration and transformation mechanism of heavy metals during the washing-thermal treatment process, and provide a reference for the safe disposal and resource utilization of fly ash.

No related articles found!
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
[1] . Optimization Study on Effect Evaluation Index for Source Separation of Municipal Solid Waste Based on F-measure   [J]. Environmental Sanitation Engineering, 2018, 26(3): 1 -3 .
[2] . Exploration and Research on Improving the Classification Effect of Domestic Garbage in Guangzhou   [J]. Environmental Sanitation Engineering, 2018, 26(3): 4 -7 .
[3] . Application on Pretreatment Technology of Food Waste in Hangzhou   [J]. Environmental Sanitation Engineering, 2018, 26(3): 8 -10 .
[4] . Characteristics and Choice of Treatment Measures of Domestic Waste Simple Landfill in the Rural of China   [J]. Environmental Sanitation Engineering, 2018, 26(3): 11 -13 .
[5] . Municipal Sewage Sludge Co-firing in Waste Incineration Power Plant: A Case Study of Hengyang City   [J]. Environmental Sanitation Engineering, 2018, 26(3): 14 -17 .
[6] . Engineering Characteristics of Bottom Ash in Municipal Solid Waste Incinerator   [J]. Environmental Sanitation Engineering, 2018, 26(3): 18 -22 .
[7] . Automatic Control of SNCR System in Waste Incineration Plant   [J]. Environmental Sanitation Engineering, 2018, 26(3): 23 -25 .
[8] . Ways and Efficiency Analysis of Landfill Gas Utilization in Beijing Liulitun Landfill   [J]. Environmental Sanitation Engineering, 2018, 26(3): 26 -28 .
[9] . Study on Influencing Factors of Municipal Solid Waste Heating Value in Taiyuan   [J]. Environmental Sanitation Engineering, 2018, 26(3): 29 -32 .
[10] . Inhibition Concentration and Elimination Method of Ammonia Nitrogen in Anaerobic Digestion Process   [J]. Environmental Sanitation Engineering, 2018, 26(3): 33 -35 .
Copyright © Environmental Sanitation Engineering
Address: 107#, Weidi Road, Tianjin, P.R.C.    Postcode: 300201
Telephone: 022-28365069   Fax: 022-28365080 E-mail: csglwyjs10@tj.gov.cn
Supported by:Beijing Magtech