环境卫生工程 ›› 2022, Vol. 30 ›› Issue (6): 64-69.doi: 10.19841/j.cnki.hjwsgc.2022.06.011

• 危险废物利用、处理与处置 • 上一篇    下一篇

矿物组分对生活垃圾焚烧飞灰熔融特性的影响

张春飞,胡彦弢,张建东,陈瑶姬,戴豪波   

  1. 1. 西安航天源动力工程有限公司;2. 浙江天地环保科技股份有限公司
  • 出版日期:2023-01-04 发布日期:2023-01-04

Study on the Effect of Mineral Compositions on the Melting Characteristics of Fly Ash from MSW Incineration

ZHANG Chunfei, HU Yantao, ZHANG Jiandong, CHEN Yaoji, DAI Haobo   

  1. 1. Xi’an Aerospace Yuan Dongli Engineering Co. Ltd.;2. Zhejiang Tiandi Environmental Protection Technology Co. Ltd.
  • Online:2023-01-04 Published:2023-01-04

摘要: 根据某垃圾焚烧电厂产生的飞灰组分特性,分析单组分及双组分不同配伍比例对飞灰熔融温度的影响。结果表明:飞灰中添加SiO2可以显著降低飞灰的熔融温度,特别是在添加质量分数为0~5%时,每增1%,对灰熔点的降低范围为 14~21 ℃。Al2O3添加比例在10%内能降低飞灰的灰熔点,但添加比例在10%~25%时反而提升飞灰的熔融特征温度。CaO 和MgO均能提升飞灰的熔融特征温度,CaO提升的作用较大。酸性氧化物含量较高的粉煤灰对飞灰能起到明显助熔作用。在碱度平衡的条件下,添加二元组分SiO2-MgO和SiO2-CaO会进一步降低熔融温度,SiO2-MgO较SiO2-CaO助熔效果更明显,相反,添加二元组分Al2O3-MgO和Al2O3-CaO会显著提高飞灰的熔融温度。

关键词: 飞灰, 组分, 熔融温度, 配伍

Abstract: According to the component characteristics of fly ash produced by a MSW incineration power plant, the effects of different compatibility ratios of single component and two components on the melting temperature of fly ash were analyzed. The results indicated that the addition of SiO2 could significantly reduce the melting temperature of fly ash, especially for every 1% step increased when the adding mass fraction was 0~5%, the reduction of ash melting temperature was about 14~21 ℃. The addition ratio of Al2O3 could decrease the ash melting point of fly ash within 10% , but it could increase the melting characteristic temperature of the fly ash when the proportion was 10%~25%. Both CaO and MgO could increase the melting characteristic temperature of fly ash, and CaO could have a great effect. Coal ash with high content of acid oxides could obviously promote the melting of fly ash. Under the condition of alkalinity balance, the addition of binary components SiO2-MgO and SiO2-CaO would further reduce the melting temperature, and the melting aid effect of SiO2-MgO was more obvious than SiO2-CaO. On the contrary, the addition of binary components Al2O3-MgO and Al2O3-CaO would significantly increase the melting temperature of fly ash.

Key words: fly ash, composition, melting temperature, compatibility

[1] 张 喆, 邹良栋, 王永康, 王一迪, 罗中力, 王 伟. 固化/稳定化飞灰在酸性环境中重金属浸出行为研究[J]. 环境卫生工程, 2022, 30(5): 72-82.
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