环境卫生工程 ›› 2023, Vol. 31 ›› Issue (4): 63-69.doi: 10.19841/j.cnki.hjwsgc.2023.04.011

• 建筑垃圾利用、处理与处置 • 上一篇    下一篇

固废基硫铝系高活性材料改性磷石膏制备路面基层材料试验研究

肖 心,李敬伟,侯祥山,贾爱光,王文龙,毛岩鹏   

  1. 山东大学 能源与动力工程学院,燃煤污染物减排国家工程实验室,环境热工技术教育部工程研究中心,山东省能源碳减排技术与资源化利用重点实验室,山东省固废绿色材料工程实验室
  • 出版日期:2023-08-31 发布日期:2023-08-31

tudy on Properties of Pavement Base Material Prepared Using Phosphogypsum Modified by Solid Waste-based Sulfoaluminate High-activity Material

XIAO Xin, LI Jingwei, HOU Xiangshan, JIA Aiguang, WANG Wenlong, MAO Yanpeng   

  1. Shandong Engineering Laboratory for Solid Waste Green Materials, Shandong Key Laboratory of Energy Carbon Reduction and Resource Utilization, Engineering Research Center of Environmental Thermal Technology of Ministry of Education, National Engineering Laboratory for Reducing Emissions from Coal Combustion, School of Energy and Power Engineering,Shandong University
  • Online:2023-08-31 Published:2023-08-31

摘要: 为解决磷石膏的大规模资源化利用难题,并考虑工程应用的经济性,采用全固体废物制备的具有早强、高强、低成本优势的硫铝系高活性材料(SHAM)熟料作为主要胶凝材料,复配电石渣、矿粉等掺合料改性磷石膏以制备SHAM稳定磷石膏混合料(SSPM),并开展SSPM用作路面基层材料的试验研究。对SSPM进行了无侧限抗压强度试验、水稳定性试验及微观结构测试,研究了电石渣和矿粉对SSPM力学性能和水稳定性能的影响,并分析了其作用机理;探究了不同SHAM熟料掺加比对SSPM力学性能的影响。结果表明:SSPM的7 d无侧限抗压强度最高可达6.02 MPa,能够用作路面基层材料;掺合料可促进水化产物的生成与稳定,掺加1%的电石渣和3%的矿粉可提高SSPM任意龄期下的无侧限抗压强度;SSPM水稳定性好,软化系数均不低于0.85且浸水强度仍能满足路基材料的强度要求。随着SHAM熟料掺量的增加,SSPM的7 d和28 d强度均显著提高,但当掺量超过15%时,SSPM的后期强度有所降低。该结果可为扩大磷石膏的资源化利用提供可行技术路径,促进社会低碳循环发展。

关键词: 磷石膏, 硫铝系高活性材料, 路面基层材料, 无侧限抗压强度, 水稳定性

Abstract: In order to solve the problem of large-scale resource utilization of phosphogypsum and consider the economy of engineering application. Sulfoaluminate high-activity material (SHAM) clinker prepared from total solid waste with advantages of early strength, high strength and low cost was used as the main cementing material. Phosphogypsum was modified by admixture such as distribution stone slag and mineral powder to prepare SHAM stable phosphogypsum mixture (SSPM), and the experimental research of SSPM used as pavement base material was carried out. The unconfined compressive strength test, water stability test and microstructure test of SSPM were carried out. The effects of carbide slag and mineral powder on the mechanical properties and water stability of SSPM were studied, and the action mechanism was analyzed. The effects of different SHAM clinker ratios on the mechanical properties of SSPM were studied. The results showed that the 7d unconfined compressive strength of SSPM was up to 6.02 MPa, which could be used as pavement base material. Admixture could promote the formation and stability of hydration products, adding 1% carbide slag and 3% mineral powder could improve the unconfined compressive strength of SSPM at any age. SSPM had good water stability, the softening coefficient was not less than 0.85, and the water-soaked strength could still meet the strength requirements of roadbed materials. With the increase of solid waste-based SHAM clinker content, the 7 d and 28 d strength of SSPM increased significantly, but the later strength of SSPM decreased when the content was more than 15%. This study could provide a feasible technological path for expanding the resource utilization of phosphogypsum and promote the development of low carbon cycle in society.

Key words: phosphogypsum, sulfoaluminate high activity material, pavement base material, unconfined compressive strength, water stability

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